نشریه علمی پژوهشی مهندسی آبیاری و آب ایران

نشریه علمی پژوهشی مهندسی آبیاری و آب ایران

تجزیه و تحلیل آلودگی نیترات با استفاده از روشهای هیدروشیمیایی و ایزوتوپ های پایدار در بخش جنوبی آبخوان بهبهان

نوع مقاله : مقاله پژوهشی

نویسندگان
1 دانشجوی دکتری هیدروژئولوژی دانشکده علوم زمین، دانشگاه شهید چمران ، اهواز ، ایران
2 کارشناس سازمان آب و برق خوزستان، اهواز، ایران
3 استاد دانشکده علوم زمین، دانشگاه شهید چمران، اهواز ،ایران
4 دانشکده علوم زمین ، دانشگاه شهید بهشتی، تهران،ایران
5 ، گروه مهندسی محیط زیست، دانشگاه آزاد اسلامی، واحد تهران شمال،ایران
6 کارشناس شرکت آب منطقه ای کهگیلویه و بویر احمد،یاسوج ایران
10.22125/iwe.2025.500969.1850
چکیده
در بسیاری از مناطق خشک و نیمه خشک، به علت عدم وجود منابع آب سطحی و یا به دلیل آلودگی، کمبود بارندگی و تبخیر شدید ناشی از تغییرت آب و هوایی این منبع حیاتی در دسترس نمی باشد.کمبود این منبع ارزشمند باعث شده تا آب زیرزمینی مهمترین منبع تامین آب جهت مصارف مختلف در این مناطق باشد. ولی کیفیت این منابع نیز عمدتاٌ به دلیل فعالیت های انسان زاد از قبیل تولید فاضلاب های خانگی و صنعتی و همچنین استفاده از کودهای شیمیایی به شدت رو به کاهش است. بنابراین، شناسایی منابع آلاینده برای محافظت از کیفیت منابع آب زیرزمینی موضوعی مهم و ضروری است. هدف این پژوهش بررسی آلودگی نیترات در چاه های کم عمق بخش جنوبی آبخوان بهبهان با استفاده از روش‏های هیدروشیمیایی و ایزوتوپهای پایدار می باشد. برای نیل به هدف، تعداد 56 نمونه آب (8 نمونه آب سطحی،3 نمونه زه آب کشاورزی و 45 نمونه آب زیرزمینی) جهت آنالیز آنیونها و کاتیونهای اصلی، عناصر فرعی و ایزوتوپ های پایدار δ18Oو δD جمع آوری شد. نتایج بدست آمده با استفاده از نرم افزارهای آماری SPSS وXLSTAT ، مورد تجزیه و تحلیل قرارگرفت.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Analysis of nitrate pollution using hydrochemical methods and stable isotopes in the southern part of Behbahan aquifer

نویسندگان English

nahid zarvash 1
Hsan Daneshyan 2
nasralah kalantari 3
Farshad Alijani 4
Ali Afros 5
Mohammad Bashti 6
1 Ph.D. Student, Department of Geology, Faculty of Earth Science, Shahid Chamran University of Ahvaz Khuzestan Power and Water Authority, Ahvaz,Iran
2 Khuzestan Power and Water Authority, Ahvaz,Iran
3 Professor, Department of Geology, Faculty of Earth Science, Shahid Chamran University of Ahvaz, Iran
4 Faculty of Earth Sciences, University of Shahid Beheshti, Tehran, Iran
5 Assistant Professor, Department of Environmental Engineering, North Tehran Branch, Islamic Azad University, Iran
6 Kohgiloueh and Boyer Ahmad Regional Water Company, Yasooj, Iran
چکیده English

In many arid and semi-arid areas, due to lack of surface water or pollution, rainfall deficiency, and intense evaporation as a result of climatic conditions, this precious resource is limited. The defect of this vital resource resulted in groundwater being exploited for different purposes in such areas. However the quality of groundwater is subjected to contamination due to human activities such as domestic wastewater, industry, manure, and fertilizer. Therefore, pollution source detection as a significant subject is necessary. This investigation aimed to evaluate nitrate pollution in shallow wells in the southern part of the Behbehan aquifer using hydrochemical and stable isotopes. To achieve the goal, 56 samples ( 8 surface water, 3 drain water, and 45 groundwater) were collected for major, minor elements and stable isotope analysis.. The collected data was interpreted by SPSS and XLSTAT statistical software. The data indicated that the nitrate concentration varies between 3 to 103 mg/l and δD and δ18O ranges between -17.5 to -3.5 and -5 to 1.75 respectively. Nitrate ion concentration variation and well depth revealed that around Behbehan City and surrounding villages where well depth is below 30 m, the nitrate concentration was between 40 to 103 mg/l, indicating anthropogenic activities including domestic wastewater and manure controlling increasing nitrate concentration.

کلیدواژه‌ها English

Publication of nitrate
isotope
Behbahan underground water
hydrochemistry
محمدزاده، ح.، اسکندری، ع. 1397. استفاده از تکنیکهای هیدروژئوشیمیایی و ایزوتوپی  به منظو ر  فهم بهتر ویژگیهای   منابع آبی مهم محدوده های مطالعاتی پاوه و جوانرود، استان کرمانشاه. مجله  هیدروژئولوژی تبریز، دوره سوم، شماره 1 ،80-98.
دانشیان،ح، کلانتری،ن. 1397. ارزیابی کارکرد شبکه های آبیاری در بالاآمدگی سطح آب زیرزمینی (مطالعه موردی: دشت بهبهان)اکو هیدرولوژی، 135-148
زریاب, ع. ناصری,ح. ر. علیجانی ، ف. 1401. شناسایی منشأ و سهم نسبی نیترات در آبخوان شرقی کابل با استفاده از نمایانگر‌های ایزوتوپی و مدل BSIMM. فصلنامه علوم محیطی, 22(4), 557-570.
Aleku, D.L., Dähnke, K. and Pichler, T., 2024. Source, transport, and fate of nitrate in shallow groundwater in the eastern Niger Delta. Environmental Science and Pollution Research, 31(56), pp.65034-65050.
Alex, R., Kitalika, A., Mogusu, E., & Njau, K. 2021. Sources of nitrate in ground water aquifers of the semiarid region of Tanzania. Geofluids, 2021, 1-20.
Adimalla, N., & Wu, J. 2019. Groundwater quality and associated health risks in a semi-arid region of south India: Implication to sustainable groundwater management. Human and ecological risk assessment: an international journal, 25(1-2), 191-216.
Bian, J.M., Liu, C.H., Zhang, Z.Z., Wang, R., Gao, Y., 2016. Hydro-geochemical characteristics and health risk evaluation of nitrate in groundwater. Pol. J. Environ. Stud. 25 (2), 521–527.
Belkhiri, L., Boudoukha, A., Mouni, L. 2011. A multivariate statistical analysis of groundwater chemistry data. International Journal of Environmental Research 5(2):537-544.
Furi, P. 2011. Hydrochemical characterization of complex volcanc aquifers in a continental rifted zone: the middle Awash basin. Hydrogeol J 20:385–400.
Fritz, P. Fontes, J.C., 1980. Introduction. In: Fritz P, Fontes JC (eds) Handbook of environmental isotope geochemistry, 1st edn. Elsevier, Amsterdam, pp 1–19.
Gleeson, T., Cuthbert, M., Ferguson, G., & Perrone, D. 2020. Global groundwater sustainability, resources, and systems in the Anthropocene.Annual review of earth and planetary sciences, 48 , 431-463.
Guo, Z., Yan, C., Wang, Z., Xu, F., Yang, F., 2020. Quantitative identification of nitrate sources in a coastal peri-urban watershed using hydrogeochemical indicators and dual isotopes together with the statistical approaches. Chemosphere 243, 125364.
Han, D.M., Liang, X., Jin, M.G., Currell, M.J., Song, X.F. and Liu, C.M., 2010. Evaluation of groundwater hydrochemical characteristics and mixing behavior in the Daying and Qicun geothermal systems, Xinzhou Basin. Journal of Volcanology and Geothermal Research, 189(1-2), pp.92-104.
He, C., Liu, Z., Wu, J., Pan, X., Fang, Z., Li, J., & Bryan, B. A. 2021. Future global urban water scarcity and potential solutions.Nature communications, 12 (1), 1-11.
He, S., Li, P., Su, F., Wang, D. and Ren, X., 2022. Identification and apportionment of shallow groundwater nitrate pollution in Weining Plain, northwest China, using hydrochemical indices, nitrate stable isotopes, and the new Bayesian stable isotope mixing model (MixSIAR). Environmental pollution, 298, p.118852.
Jasechko, S. Global Isotope Hydrogeology—Review. Rev. Geophys. 2019, 57, 835–965.
Khmila, K., Trabelsi, R., Zouari, K., Kumar, U.S .2021. Application of geochemical and isotopic tracers for the evaluation of groundwater quality in the irrigated area of the Sbiba plain (Central West Tunisia). Agr Ecosyst Environ 313:107298.
Krimsky, L.S., Lusk, M.G., Abeels, H., Seals, L., 2021. Sources and concentrations of nutrients in surface runoff from waterfront homes with different landscape practices. Sci. Total Environ. 750, 142320.
Kumar, P.S., Elango, L., James, E., 2014. Assessment of hydrochemistry and groundwater quality in the coastal area of South Chennai, India. Arab J Geosci 7:2641–2653.
Li, P., Karunanidhi, D., Subramani, T., Srinivasamoorthy, K., 2021. Sources and consequences of groundwater contamination. Arch. Environ. Contam. Toxicol. 80 (1), 110.
Li, P., Tian, R., Xue, C., & Wu, J. 2017. Progress, opportunities, and key fields for groundwater quality research under the impacts of human activities in China with a special focus on western China. Environmental Science and Pollution Research, 24, 13224-13234.
Mohammadzadeh, H., Eskandari Mayvan, J. and Heydarizad, M., 2020. The effects of moisture sources and local parameters on the 18O and 2H contents of precipitation in the west of Iran and the east of Iraq. Tellus B: Chemical and Physical Meteorology, 72(1), pp.1-15.
Marques, J.M., Eggenkamp, H.G., Graça, H., Carreira, P.M., Jose, Matias M, Mayer B, Nunes D (2010) Assessment of recharge and flowpaths in a limestone thermomineral aquifer system using environmental isotope tracers (Central Portugal). Isotopes Environ Health Stud 46:156–165.
Martínez J A T; Mora A ; Mahlknecht J ; Daessle L W; , Aviles P A C; , Rogelio Ledesma-Ruiz R L.2021. Estimation of nitrate pollution sources and transformations in groundwater of an intensive livestock-agricultural area (Comarca Lagunera), combining major ions, stable isotopes and MixSIAR model. Environmental Pollution 269 (2021) 115445.
Piper, A.M., 1944. A graphic procedure in the geochemical interpretation of water- analyses. Trans. Am. Geophys. Union 25 (6), 914–928.
Parnell, A.C., Inger, R., Bearhop, S. and Jackson, A.L., 2010. Source partitioning using stable isotopes: coping with too much variation. PloS one, 5(3), p.e9672.
Panno, S. V., Hackley, K. C., Hwang, H. H., Greenberg, S. E., Krapac, I. G., Landsberger, S., & O'kelly, D. J. 2006. Characterization and identification of Na‐Cl sources in ground water. Groundwater, 44(2), 176-187.
Ramaroson, V., Randriantsivery, J.R., Rajaobelison, J., Fareze, L.P., Rakotomalala, C.U., Razafitsalama, F.A. and Rasolofonirina, M., 2020. Nitrate contamination of groundwater in Ambohidrapeto–Antananarivo-Madagascar using hydrochemistry and multivariate analysis. Applied Water Science, 10(7), pp.1-13.
She, W., Jiao, Y., Lu, R., Chai, Y., Chen, F., Shen, J., Zhang, H., Liao, H. and Xu, Q.E., 2024. Quantification of Nitrate Sources and Its Spatial Heterogeneity by Dual Isotopes. Ecosystem Health and Sustainability, 10, p.0201.
Strebel, O.W.H.M., Duynisveld, W.H.M. and Böttcher, J., 1989. Nitrate pollution of groundwater in western Europe. Agriculture, ecosystems & environment, 26(3-4), pp.189-214.
Sappa, G., Vitale, S. and Ferranti, F., 2018. Identifying karst aquifer recharge areas using environmental isotopes: A case study in central Italy. Geosciences, 8(9), p.351.
Tijani, M.N. and Abimbola, A.F., 2003. Groundwater chemistry and isotope studies of weathered basement aquifer: a case study of Oke-Ogun area, SW-Nigeria. Africa Geoscience Review, 10(4), pp.373-388.
Tesoriero, A.J., Liebscher, H. and Cox, S.E., 2000. Mechanism and rate of denitrification in an agricultural watershed: Electron and mass balance along groundwater flow paths. Water resources research, 36(6), pp.1545-1559.
Widory, D., Petelet-Giraud, E., N´egrel, P., Ladouche, B., 2005. Tracking the sources of nitrate in groundwater using coupled nitrogen and Boron isotopes:A Synthesis. Environ. Sci. Technol. 39 (2), 539–548.
Weitzman, J.N., Brooks, J.R., Mayer, M.P., Rugh, W.D., Compton, J.E., 2021. Coupling the dual isotopes of water (δ2H and δ18O) nitrate (δ15N and δ18O): a new framework for classifying current and legacy groundwater pollution. Environmental Research Letter, 16, 045008. .
Xia, Y., Li, Y., Zhang, X. and Yan, X., 2017. Nitrate source apportionment using a combined dual isotope, chemical and bacterial property, and Bayesian model approach in river systems. Journal of Geophysical Research: Biogeosciences, 122(1), pp.2-14.
Xu, G., Su, X., Yuan, Z., Ji, L., Li, N., Liang, H. 2021. Nitrogen behavior during artificial groundwater recharge through ponds: a case study in Xiong’an New Area. Environ. Geochem. Health.
Zhou, Y., Li, P., Peiyue, L., Chen, M., Dong, Z., Lu, C. 2020. Groundwater quality for potable and irrigation uses and associated health risk in southern part of Gu’an County, North China Plain. Environ Geochem Health 43:813–835.
Wei, X., Zhou, Y., Ran, L., Chen, M., Zou, J., Fan, Z. and Fu, Y., 2024. Sources and Transformation of Nitrate in Shallow Groundwater in the Three Gorges Reservoir Area: Hydrogeochemistry and Isotopes. Water, 16(22), p.3299